Orthorhombic System
The orthorhombic system is defined by three mutually perpendicular axes, all of which have unequal lengths.
Geometrically, it takes the shape of a rectangular prism. It is a unique and highly versatile system in crystallography, as it is the only one that accommodates all four Bravais lattice types: primitive ($P$), base-centered ($C$), body-centered ($I$), and face-centered ($F$).
From a symmetry perspective, it is characterized by three mutually perpendicular two-fold rotation axes or mirror planes. Because the edge lengths are all different ($a$, $b$, and $c$), physical properties like electrical conductivity or refractive index often vary depending on the direction of measurement, a phenomenon known as anisotropy.
Lattice parameters: $a \neq b \neq c$, and angles $\alpha = \beta = \gamma = 90^\circ$.
Examples: Alpha-Sulfur (rhombic), Olivine, Topaz, and Aragonite.
Geometric Constraints
a=2.46, b=2.952, c=3.69
α=90°, β=90°, γ=90°
Grid Expansion
Appearance
Coordination